https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47997 Tue 14 Feb 2023 16:15:07 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:39230 −1 of As(V)]. Besides, it was observed that available soil phosphorus could positively affect the relative content of water-soluble, exchangeable and carbonate-bound arsenic. In the kinetics experiment, both the Michaelis-Menten constant (K_m) and maximum reaction velocity (V_max) of ALP increased with increasing As(V) concentration under four months ageing for each size aggregate. Multiple linear stepwise regression analysis between k_cat and the relative content of arsenic fraction indicated that carbonate-bound arsenic is the main fraction that inhibited the k_cat for macroaggregates (> 0.25 mm size). For soil aggregates of 0.1–0.25 mm size, k_cat increased with an increase in arsenic residual fraction. As for aggregates <0.1 mm size, Fe and Mn oxide-bound fraction is the main fraction that inhibited the k_cat. Overall, this study suggests carbonate-bound and Fe and Mn oxide-bound arsenic fractions could decrease the ALP activities via a decrease in the catalytic efficiency in macroaggregates and <0.1 mm size aggregates, respectively. Besides, available phosphorus should be considered as the main factor when assessing As biotoxicity and mobility.]]> Tue 09 Aug 2022 14:08:44 AEST ]]>